Tunable Molecular Interactions Near an Atomic Feshbach Resonance: Stability and Collapse of a Molecular Bose-Einstein Condensate
Abstract
Understanding and controlling interactions of ultracold molecules has been a central goal in quantum chemistry research. Recent experiments on atoms near a Feshbach resonance offer the key to prepare and investigate molecules in the quantum many-body regime. Just as Feshbach resonances allow tuning of the scattering length of bosonic atoms, we show that they also modify the scattering length of Feshbach molecules which are constituted from these atoms. Based on calculations of the compressibility, we determine the stability phase diagrams of molecular condensates and show that their instability can be associated with a sign change of the inter-molecular interactions. We derive universal expressions for the molecular scattering lengths, presented in terms of experimentally measurable quantities. These will enable control of interactions between Feshbach molecules as well as further studies of few- and many-body reactions involving Feshbach molecules in the quantum regime.