CyberSec Research

In this paper, we extend our recent work on cesium S and D states [Phys. Rev. Lett. 133, 233005 (2024)] to the F states. We present absolute frequency measurements of the $|6S_{1/2}, F = 3\rangle \rightarrow nF_{5/2,7/2}(n = 28-68)$ Rydberg series to measure the spectrum of $^{133}$Cs. Atomic spectra are obtained using a three-photon excitation scheme referenced to an optical frequency comb in a sample of ultracold $^{133}$Cs. By globally fitting the absolute-frequency measurements to the modified Ritz formula, we determine the quantum defects of the $nF_{5/2}$ and $nF_{7/2}$ series. The ionization potential extracted for both series from the modified Ritz formula agrees with our measurements based on the S and D series. Fine-structure intervals are calculated and parameterized. The wave functions computed for the energies from the quantum defects are used to calculate transition dipole moments. We compare the reduced electric-dipole matrix elements with available benchmarks and find agreement within the precision of those works. The scalar and tensor polarizabilities of the $nS_{1/2}$, $nP_J$ , $nD_J$ and $nF_J$ series are calculated based on the now more accurate set of wave functions. Moreover, we report the polarizability as a series in powers of the effective principal quantum number and find the main coefficients of the expansion. The results will be useful for calculating properties of $^{133}$Cs such as collision and decay rates, polarizabilities, and magic wavelengths.

The recent breakthroughs in the distribution of quantum information and high-precision time and frequency (T&F) signals over long-haul optical fibre networks have transformative potential for physically secure communications, resilience of Global Navigation Satellite Systems (GNSS) and fundamental physics. However, so far these capabilities remain confined to isolated testbeds, with quantum and T&F signals accessible, for example in Germany, to only a few institutions. We propose the QTF-Backbone: a dedicated national fibre-optic infrastructure in Germany for the networked distribution of quantum and T&F signals using dark fibres and specialized hardware. The QTF-Backbone is planned as a four-phase deployment over ten years to ensure scalable, sustainable access for research institutions and industry. The concept builds on successful demonstrations of high-TRL time and frequency distribution across Europe, including PTB-MPQ links in Germany, REFIMEVE in France, and the Italian LIFT network. The QTF-Backbone will enable transformative R&D, support a nationwide QTF ecosystem, and ensure the transition from innovation to deployment. As a national and European hub, it will position Germany and Europe at the forefront of quantum networking, as well as time and frequency transfer.

The finite operators are derived for the recoil $m\alpha^6(m/M)$ order relativistic corrections (to spin-averaged energy levels) in hydrogen-like atoms and ions in the two- and three-body formalism beyond the adiabatic approximation. Results are presented in a form suitable for numerical evaluation.

Advancing the temporal resolution in computations, signal generation and modulation, and measurements is of paramount importance for pushing the boundaries of science and technology. Optical resonators have recently demonstrated the ability to perform computational operations at frequencies beyond the gigahertz range, surpassing the speed of conventional electronic devices. However, increasing the resonator length extends the operation time but decreases the temporal resolution, with current state-of-the-art systems achieving only picosecond resolution. Here we show that atoms and molecules belong to the class of widely-used passive resonators that operate without gain, such as subwavelength particles, electric circuits, and slabs, but with long operation times and, importantly, attosecond resolution. Our analysis reveals that when resonantly exciting atoms and molecules, the resulting scattered field is the integral of the incoming field envelope, with improvement factors in temporal resolution of a million and trillion compared with optical resonators and electronic devices, respectively. We demonstrate our results theoretically for atoms and compare it with the standard slab resonator. Remarkably, our approach applies to all transition types including electronic, vibrational, rotational, and spin, with the same temporal resolution preserved across all frequencies. Our research paves the way for a new generation of devices operating on attosecond timescales and opens new avenues in fields such as computation, ultrafast phenomena, high-rate data transmission, encryption, and quantum technology.

Metal hydrogen exhibiting electron delocalization properties has been recognized as an important prospect for achieving controlled nuclear fusion, but the extreme pressure conditions required exceeding hundreds of GPa remain a daunting challenge. Here, we propose a model of superatomic hydrogen, aiming to reduce the pressure conditions required for the effective aggregation of elemental hydrogen atoms. High-precision ab initio calculations indicate that the pressure required to compress the H13 system with one central atom and 12 surrounding atoms into a superatomic state is approximately two orders of magnitude lower than that of metallic hydrogen. Atomic-level analyses reveal that in the superatomic state of compressed H13, the central H atom donates its electron, and all electrons are delocalized on the superatomic molecular orbitals, which conforms to properties of metallic hydrogen. Our discovery in principle opens up the prospect of superatomic hydrogen in areas such as nuclear fusion.

Widely used in atomic and superconducting qubit systems, the Jaynes-Cummings (JC) Hamiltonian is a simple, yet powerful model for a two-level system interacting with a quantum harmonic oscillator. In this paper, we focus on a system of n qubits, identically coupled to a single oscillator via JC interaction, also known as the Tavis-Cummings (TC) Hamiltonian. We show that all permutationally-invariant unitaries on an arbitrary number of qubits can be realized using this permutationally-invariant Hamiltonian, which couples the qubits to an oscillator initialized in its vacuum state, together with global uniform x and z fields on all qubits. This includes useful gates, such as controlled-Z gate with an arbitrary number of control qubits. As a corollary, we find that all permutationally invariant states -- including useful entangled states such as GHZ and Dicke states -- can be prepared using this interaction and global fields. We also characterize unitaries that can be realized on the joint Hilbert space of the qubits and oscillator with the TC interaction and global z field, and develop new methods for preparing the state of the oscillator in an arbitrary initial state. We present various examples of explicit circuits for the case of n=2 qubits. In particular, we develop new methods for implementing controlled-Z, SWAP, iSWAP, and $\sqrt{i\text{SWAP}}$ gates using only the TC interaction and a global z field. Our work also reveals an accidental symmetry in the TC Hamiltonian and shows that it can be explained using Schwinger's oscillator model of angular momentum.

We investigate the time evolution of a non-resonant dressed-atom qubit in an XZ original configuration. It is composed of two electromagnetic fields, one oscillating parallel and the other orthogonal to the quantisation magnetic static field. The experiments are performed in rubidium and caesium atomic magnetometers, confined in a magneto-optical trap and in a vapour cell, respectively. Static fields in the $\mu$T range and kHz oscillating fields with large Rabi frequencies are applied. This dual-dressing configuration is an extension of the Landau-Zener multipassage interferometry in the presence of an additional dressing field controlling the tunneling process by its amplitude and phase. Our measurement of the qubit coherence introduces additional features to the transition probability readout of standard interferometry. The coherence time evolution is characterized by oscillations at several frequencies, each of them produced by a different quantum contribution. Such frequency description introduces a new picture of the qubit multipassage evolution. Because the present low-frequency dressing operation does not fall within the standard Floquet engineering paradigm based on the high-frequency expansion, we develop an ad-hoc dressing perturbation treatment. Numerical simulations support the adiabatic and non-adiabatic qubit evolution.

Here, we report the first demonstration of laser-induced conversion electron M\"{o}ssbauer spectroscopy of the $^{229}$Th nuclear isomeric state, which provides the ability to probe the nuclear transition in a material that is opaque to light resonant with the nuclear transition. Specifically, we excite the nuclear transition in a thin ThO$_2$ sample whose band gap ($\sim$ 6 eV) is considerably smaller than the nuclear isomeric state energy (8.4 eV). As a result, the excited nucleus can quickly decay by internal conversion, resulting in the ejection of electrons from the surface. By collecting these conversion electrons, nuclear spectroscopy can be recorded. Unlike fluorescence spectroscopy, this technique is compatible with materials whose work function is less than the nuclear transition energy, opening a wider class of systems to study. Further, because ThO$_2$ can be made from spinless isotopes and the internal conversion decay process reduces the isomeric state lifetime to only $\sim$10 $\mu$s, allowing $\sim$10$^8$ relative reduction in clock interrogation time, a conversion-electron-based nuclear clock could lead to a $\sim$10$^4$ reduction in clock instability.

A key advantage of quantum metrology is the ability to surpass the standard quantum limit for measurement precision through the use of non-classical states. However, there is typically little to no improvement in precision with the use of non-classical states for measurements whose duration exceeds the decoherence time of the underlying quantum states. Measurements aimed at the ultimate possible precision are thus performed almost exclusively with classical states and, therefore, are constrained by the standard quantum limit. Here, we demonstrate that by using the phenomenon of subharmonic excitation, in combination with a recently demonstrated technique of Raman excitation of a harmonic oscillator, the frequency of an electric field can be measured at a resolution below the standard quantum limit of the corresponding linear measurement. As the input states can be classical, this metrological gain persists to long timescales and improves the ultimate possible precision. While we demonstrate this technique using motional Raman subharmonic excitation of a single 40ca^+ ion through engineered Floquet states, this technique is expected to be extendable to other platforms, such as NV centers, solid-state qubits, and neutral atoms, where it can provide metrological gain for sensing across the radio frequency, microwave, and optical domains.

We investigate spectral singularities in an alkali-metal atomic vapor modeled using four and effectively three hyperfine states. By comparing the eigenvalue spectra of a non-Hermitian Hamiltonian (NHH) and a Liouvillian superoperator, we analyze the emergence and characteristics of both semiclassical and quantum exceptional points. Our results reveal that, for atomic systems, the NHH approach alone may be insufficient to fully capture the system's spectral properties. While NHHs can yield accurate predictions in certain regimes, a comprehensive description typically requires the Liouvillian formalism, which governs the Lindblad master equation and explicitly incorporates quantum jump processes responsible for repopulation dynamics. We demonstrate that the inclusion of quantum jumps fundamentally alters the spectral structure of the system. In particular, we present examples in which the existence, location in parameter space, or even the order of spectral degeneracies differ significantly between the two approaches, thereby highlighting the impact of quantum jumps and the limitations of the NHH method. Finally, using the hybrid-Liouvillian formalism, we show how quantum jumps reshape spectral features initially predicted by the NHH, ultimately determining the full Liouvillian spectrum.

For the bound-muon decay process, the study of atomic effects on the electron spectrum near its endpoint is performed within the framework of the Fermi effective theory. The analysis takes into account for corrections due to finite-nuclear-size, nuclear-deformation, electron-screening, and vacuum-polarization effects, all of which are incorporated self-consistently into the Dirac equation. Furthermore, the nuclear-recoil correction to the muon binding energy is included. Calculations are carried out for the isotopes of C, Al, and Si, which are of a particular importance for forthcoming experiments aimed at search for the charged-lepton flavor-violating process of muon-to-electron conversion in a nuclear field.

Magneto-optical trapping of molecules has thus far been restricted to molecules with $^2\Sigma$ electronic ground states. These species are chemically reactive and only support a simple laser cooling scheme from their first excited rotational level. Here, we demonstrate a magneto-optical trap (MOT) of aluminum monofluoride (AlF), a deeply bound and intrinsically stable diatomic molecule with a $^1\Sigma^+$ electronic ground state. The MOT operates on the strong A$^1\Pi\leftarrow{}$X$^1\Sigma^+$ transition near 227.5~nm, whose Q$(J)$ lines are all rotationally closed. We demonstrate a MOT of about $6\times 10^4$ molecules for the $J=1$ level of AlF, more than $10^4$ molecules for $J=2$ and $3$, and with no fundamental limit in going to higher rotational levels. Laser cooling and trapping of AlF is conceptually similar to the introduction of alkaline-earth atoms into cold atom physics, and is key to leveraging its spin-forbidden a$^3\Pi \leftarrow{}$X$^1\Sigma^+$ transition for precision spectroscopy and narrow-line cooling.

Structured light, when strongly focused, generates highly confined vectorial electromagnetic field distributions which may feature a polarization component along the optical axis. Manipulating and detecting such 3D light fields is challenging, as conventional optical elements and detectors do not interact with the axial polarization component. Vector light can, however, be mapped onto atomic polarizations, making electric dipole transitions an ideal candidate to sense such 3D light configurations. Working in the hyperfine Paschen-Back regime, where the electric dipole transitions are spectrally resolved, we demonstrate direct evidence of the axial polarization component of strongly focused radial light. We investigate the influence of various input polarization states, including radial, azimuthal, and higher-order optical vortices, on atomic absorption profiles. Our results confirm a clear mapping between the 3D vector light and the atomic transition strength. This work provides new insights into vectorial light-matter interaction, and opens avenues for novel quantum sensing applications.

The sensitivity of an atom gradiometer aiming to detect gravitational waves (GW) is impacted by fluctuations of Earth's gravity field also called Newtonian Noise (NN). Sensor arrays have proved to be a promising technique for NN reduction. In our study, we further investigate the benefits of Atom Interferometer (AI) networks by improving their geometry and the extraction of the GW signal. We focus on Seismic Newtonian Noise in the frequency band from 0.1 to 10 Hz. On one hand, we show that using a specific detector geometry, a better NN rejection can occur optimizing the number of gradiometers in the network. On the other hand, we show that carrying out optimization in sub frequency bands - which results in using various detector geometries from a common network - allows even higher NN rejection while keeping a similar number of interferometers.

We present a comprehensive analysis of four-body scattering in one-dimensional (1D) quantum systems using the adiabatic hyperspherical representation (AHR). Focusing on dimer-dimer collisions between two species of fermions interacting via the sinh-cosh potential, we implement the slow variable discretization (SVD) method to overcome numerical challenges posed by sharp avoided crossings in the potential curves. Our numerical approach is benchmarked against exact analytical results available in integrable regimes, demonstrating excellent agreement. We further explore non-integrable regimes where no analytical solutions exist, revealing novel features such as resonant enhancement of the scattering length associated with tetramer formation. These results highlight the power and flexibility of the AHR+SVD framework for accurate few-body scattering calculations in low-dimensional quantum systems, and establish a foundation for future investigations of universal few-body physics in ultracold gases.

We demonstrate rapid loading of a magneto-optical trap (MOT) of cadmium atoms from a pulsed cryogenic helium buffer gas beam, overcoming strong photoionization losses. Using the $ ^1S_0 \rightarrow{} ^1P_1 $ transition at 229 nm, we capture up to $ 1.1(2) \times 10^7$ $^{112}$Cd atoms in 10 ms, achieving a peak density of $2.5 \times 10^{11}$cm$^{-3}$ and a phase-space density of $ 2 \times 10^{-9} $. The large scattering force in the deep ultraviolet enables Zeeman slowing within 5 cm of the trap, yielding a capture velocity exceeding 200 m/s. We measure the MOT trap frequency and damping constant, and determine the absolute photoionization cross section of the $^1P_1 $ state. Photoionization losses are mitigated via dynamic detuning of the trapping light's frequency, allowing efficient accumulation of multiple atomic pulses. Our results demonstrate the benefits of deep-UV (DUV) transitions and cryogenic beams for loading high-density MOTs, especially for species with significant loss channels in their main cooling cycle. The cadmium MOT provides a robust testbed that benchmarks our DUV laser cooling system and establishes the foundation for trapping and cooling polar AlF molecules, which share many optical and structural properties with Cd.

Realizing strong interactions between individual photons is a cornerstone for advancing photonic quantum computing and quantum nonlinear optics. Here, we experimentally demonstrate strong interactions between counter-propagating photons mediated by Rydberg polaritons, achieving a record-long anti-correlation range exceeding $1~\mu s$. This extended range enables the use of photon pulses that are long enough to fit within the polariton bandwidth, yet short enough to remain within the interaction range. Under these conditions, we observe complete photon blockade of entire pulses, tunable by the pulse timing, thus demonstrating the potential for controlled, deterministic operations. Extending to the three-photon regime, we observe enhanced interactions when a photon encounters two counter-propagating photons. Our results, supported by analytical theory and rigorous numerical simulations, establish counter-propagating Rydberg polaritons as a powerful platform for engineering interactions in quantum light fields.

The interaction between multilevel quantum systems and coherent radiation underlies several phenomena in modern atomic optics. The formulation and solution of the Bloch equations, which describe the dynamics of such systems, become complex as the number of levels increases. In this work, we present the Bloch Equation Generator, a free, browser-based computational tool developed to automate the generation and numerical solution of Bloch equations for systems with up to 30 levels. Users can configure the level diagram, select allowed transitions, define decay rates, and choose whether or not to apply the rotating wave approximation. The software automatically generates the complete set of equations and provides C source code for numerical solutions in both the time and frequency domains. To illustrate its applicability, we present three examples: (i) a two-level system, (ii) a $\Lambda$-type system with analysis of CPT, EIT, and the Autler-Townes effect, and (iii) a realistic 12-level system based on the Zeeman-resolved $5S_{1/2} \to 5P_{3/2}$ transition of rubidium-87.